Steam thermodynamics industrial wiki odesie by tech. Clean and pure steam systems biopharmaceutical industry. Like the pn diagram, there are regions on a ph diagram in which two phases exist together. Predominant ion boundaries are represented by lines. The pressureenthalpy diagram or ph diagram is a tool that all hvac and refrigeration engineers should be able to use proficiently. A ph diagram can be constructed for any pure substance.
Congruent phosphate control diagram trabalho premiado abtcp 2014. A ph level only a single digit away from these recommendations can make a dramatic difference. Add the engineering toolbox extension to your sketchup from the. So for example, a ph of 8 is ten times more acidic than a ph of 9, and one hundred times more acidic that a ph. Where temperature and ph favor removal of ammonia from solution. Clean steam is used in the pharmaceutical and healthcare industries in processes where the steam or its condensate can come into contact with a pharmaceutical or medical product and cause contamination. The diagram below can be used to determine enthalpy versus entropy of water and steam. In the liquidvapor region in figure 11, water and steam exist together. Figure 1 illustrates the typical ph and po 4 operating limits depending upon the operating pressure. Pressureenthalpy diagram based on iapws95 formulation for general and scientific use 200f 300f 400f 500f 600f 700 f 800f 800 f f 1200f 100f 1500f s1. A pressure enthalpy ph diagram exhibits the same features as a pn diagram. Mollier diagram pro is an easy to use mollier diagram with which you can make calculations of air treatment processes.
The points which are required for engineering calculation are from h 1 to h 6 as shown in the figure 16. This diagram describes the relationship of pressure and enthalpy of a select refrigerant. Comparison of the typical textbook diagram without arrows on the phscale axis to mathematicaltextbook diagrams e. The mollier diagram is useful when analyzing the performance of adiabatic steadyflow processes, such as flow in nozzles, diffusers, turbines and compressors. However, many useful phase diagrams can be drawn which involve variables other than t and composition. A basic understanding of thermodynamics is needed before learning how to improve plant efficiency. Rosemer and dale upgraded the widely known ph and po 4 ratio according the boiler operating pressure. Percentage of dissolved gas increases with temperature and ph. Pretreatment 44 disadvantages of ro as compared to a softener boiler pretreatment program include. Software for plotting a comparison of actual cycle ph. It comes into play with steam boilers because a ph between 7 and 9 slightly alkaline is just right. The vapor is compressed, following the constant entropy line to.
Mollier diagram for watersteam engineering toolbox. Superheated steam finds its application in steam power plants for the generation of electrical power. Clean steam in the pharmaceutical industry tim latham, m. This product can be injected into the feeding water pipe or into the hp drums. Above ph 12, virtually all the ammonia will be present as a dissolved gas. Units is to present the various properties of water and steam in a most concise form. Pressure enthalpy diagram melting line40 o 40 c2 02 0. The diagram was created in 1904, when richard mollier plotted the total heat against entropy. It is important to understand both the steadystate load profile as well as the transient and instantaneous demands. Table a1e molar mass, gas constant, and criticalpoint properties table a2e idealgas specific heats of various common gases table a3e properties of common liquids, solids, and foods table a4e saturated watertemperature table table a5e saturated waterpressure table table a6e superheated water table a7e compressed liquid water table a8e saturated icewater vapor. The international association for the properties of water and steam berlin, germany september 2008. Reviewed by faculty from other academic institutions. We know, however, that there is a limit, beyond which water can only exist as a fog of liquid water. Add standard and customized parametric components like flange beams, lumbers, piping, stairs and more to your sketchup model with the engineering toolbox sketchup extension enabled for use with the amazing, fun and free sketchup make and sketchup pro.
The diagram above shows no limit to the amount of water that can be evaporated into air. Adding steam or water liquid psychrometric chart the psychrometric chart is a variant of the mollier diagram used in some parts of the world. A refrigeration engineer commonly uses a mollier diagram ln p, h of the refrigerant used in order to represent and study the behavior of the machine with steam compression see figure 6. First commercially viable kraft mill, sweden, 1885. Vulcan recommends the water contain less than 60ppm of total dissolved solids tds and have a ph factor between 6. Steam boiler diagram with parts for dummys electrical. It is written that the cost of refrigeration is maximum. The international association for the properties of water. Steam purity versus steam quality steam purity is the condition of the steam in regards to the purity of the chemistry of the steam expressed as ppb parts per billion of tds, sodium, cation conductivity or silica in the steam steam quality is the condition of the steam in regards to the % of moisture or boiler water carryover in the steam. H 1 to h 2 is the adiabatic compression of the compressor for the simple refrigeration system without suction and discharge penalties h. In steam turbines, superheated steam enters at one end and exit from the other end into the condenser may be of water or air cooled type. If the ph is lower than that, the water will start eating the pipes. In electrochemistry, a pourbaix diagram, also known as a potentialph diagram, e hph diagram or a peph diagram, maps out possible stable equilibrium phases of an aqueous electrochemical system. The process transforming a mollier diagram to a psychrometric chart is shown below.
X steam, thermodynamic properties of water and steam. How to read mollier diagram easy explain learn and grow. I use it for optimization of installations and to accurately determine whether heat wheels work correctly rene hemme, hemmeonderhoudsadvies. This has been a useful text for the students of mechanical engineering for more than 30 years. Superheated steam and steam phase diagram electrical4u. Enthalpyentropy mollier diagram for steam mechanical. Properties of water and steam thermodynamic properties of. Of course in any phpc diagram the concentrations of all species can be read off for any phvalue that the system is titrated to, and thus major and minor species can be identified.
In power generation, thermodynamics is the conversion of chemical energy into other forms of energy this article covers thermodynamics associated with steam and fluid systems. The simplest and most straight forward use case is the generation of plots with default isolines and spacing. Below is a typical steam boiler diagram for dummys to understand with name of each component or boiler part. See also water enthalpy h and entropy s for figures and tabulated values at varying temperatures. Mollier diagram pro is the best program i have on my laptop. The pressure enthalpy diagram for steam is an excellent tool to gain an understanding of the steam tables. Engineering toolbox sketchup extension online 3d modeling. Determine the desired or necessary steam quality dryness or degree of superheat. Co 2 mollier diagram pressureenthalpy diagram mollier chart in metric units excel file 569 kb. The range between 7 and 12, both ammonium ions and dissolve gas exist together. Thermodynamics enthalpy entropy mollier and steam tables i. The xaxis of this diagram is the overall molar metal ratio in the. This is because each increasing level of ph is ten times greater than the prior level. T p sat volume,m3kg energy,kjkg enthalpy,kjkg entropy,kjkgk mpa vf vg uf ug hf hg hfg sf sg sfg 40 0.
In order to properly understand this diagram, it is best to go through the vapor compression. Po box, the heath, runcorn, cheshire, wa7 4qx tele. If its higher than that, the water wont corrode metal, but it may begin to foam, and thats not good. Attempts to readdress the types of steam used for key pharmaceutical manufacturing processes. Table a1 molar mass, gas constant, and criticalpoint properties table a2 idealgas specific heats of various common gases table a3 properties of common liquids, solids, and foods table a4 saturated watertemperature table table a5 saturated waterpressure table table a6 superheated water table a7 compressed liquid water table a8 saturated icewater vapor. Thermodynamics is the physics that deals with the relationship between heat and other forms of energy. As shown in the following figure, the ph diagram consists of pressure psia on the yaxis and enthalpy btulbm on the xaxis. Made by faculty at the university of colorado boulder, department of chemical and biological engineering.
It is advisable to use steamtables or mollier chart directly for easy and accurate estimation of the properties of steam, such as pressure, temperature, specific volume, enthalpy, entropy etc. Steam quality ranges from 0 to 100% and is defined as the ratio of. Enthalpy, entropy, mollier diagram and steam tables course no. As such a pourbaix diagram can be read much like a standard phase diagram with a different set of axes. As there is no copper tube in the system, no restrictions for the upper ph. The steam phase diagram the data provided in the steam tables can also be expressed in a graphical form. The pressureenthalpy diagram describes the liquid, vapor and mix region of water.
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